| # | Statement (Answer in bold) |
|---|---|
| 1 | An atom or a group of atoms which is responsible for chemical characteristics of an organic compound is called functional group. |
| 2 | The general molecular formula of alkynes is CnH2n-2. |
| 3 | In IUPAC name, the carbon skeleton of a compound is represented by root word. |
| 4 | Unsaturated compounds decolourize bromine water. |
| 5 | Dehydration of ethanol by concentrated sulphuric acid forms ethene. |
| 6 | 100% pure ethanol is called absolute alcohol. |
| 7 | Ethanoic acid turns blue litmus to red. |
| 8 | The alkaline hydrolysis of esters, fats or oils to form soap is termed saponification. |
| 9 | Biodegradable detergents are made of straight chain hydrocarbons. |
| Column A | Column B |
|---|---|
| Functional group | OH : Alcohol |
Answer: i) Assertion and Reason are correct, and Reason explains the Assertion.
Reason: Hydrocarbons consist of covalent bonds.
Answer: iv) Assertion and Reason are correct, but Reason does not explain the Assertion.
The simplest ketone is acetone, which is also known by its IUPAC name propanone. It is the smallest molecule that contains a carbonyl group (C=O) bonded to two alkyl groups. In the case of acetone, these alkyl groups are both methyl groups (-CH3). Its structural formula is CH3COCH3, clearly showing the central carbonyl group flanked by two methyl groups. It is a volatile, flammable liquid with a characteristic pungent odor.
(i) Propane is an acyclic saturated alkane. It is a straight-chain hydrocarbon with the molecular formula C3H8. Its structural formula is CH3-CH2-CH3, where three carbon atoms are linked by single bonds and each carbon atom is bonded to the required number of hydrogen atoms to satisfy its valency. (ii) Benzene is a cyclic aromatic hydrocarbon with the molecular formula C6H6. Its structure consists of a six-membered ring of carbon atoms with alternating single and double bonds, exhibiting resonance. (iii) Cyclobutane is an alicyclic saturated hydrocarbon with the molecular formula C4H8. It forms a four-membered ring of CH2 groups, where the carbon atoms are joined by single bonds. (iv) Furan is a heterocyclic aromatic compound with the molecular formula C4H4O. It has a five-membered ring containing four carbon atoms and one oxygen atom, with two double bonds within the ring, giving it aromatic character.
CH3CH2OH + 2[O] -> CH3COOH + H2O
Some detergents cause water pollution because they contain branched hydrocarbon chains which are not easily biodegradable. These persistent detergents remain in water bodies, leading to the formation of persistent foam and a significant reduction in water quality. Furthermore, certain detergents contain phosphates, which act as nutrients for aquatic plants. An excessive amount of phosphates can lead to eutrophication, characterized by rapid growth of algae (algal blooms). When these algae die and decompose, they consume large amounts of dissolved oxygen in the water, creating hypoxic conditions that are harmful or fatal to fish and other aquatic life. To prevent this pollution, remedial measures include using biodegradable detergents with straight-chain hydrocarbon structures, opting for phosphate-free detergent formulations, using detergents only in the required quantities, treating wastewater effectively before its discharge into natural water bodies, and avoiding the release of untreated detergent-laden water into rivers and lakes.
i. It is a sodium or potassium salt of long-chain fatty acids.
ii. The ionic part of a soap is R-COO- Na+.
iii. It is prepared from animal fats or vegetable oils.
iv. It works well in soft water, but its effectiveness is reduced in hard water.
v. It forms scum with Ca2+ and Mg2+ ions in hard water.
vi. Soaps are biodegradable.
Detergent
i. It is generally a sodium salt of sulphonic acids.
ii. The ionic part in a detergent is R-SO3- Na+.
iii. It is prepared from hydrocarbons obtained from petroleum/crude oil.
iv. It is effective even in hard water.
v. It does not form scum in hard water.
vi. It has good foaming capacity; many conventional detergents are non-biodegradable.
Characteristics:
(i) Each member differs from the preceding or succeeding member by one methylene group (-CH2), so the molecular mass differs by 14 amu.
(ii) All members contain the same elements and functional group.
(iii) They are represented by a general molecular formula, for example alkanes: CnH2n+2.
(iv) Members show a regular gradation in physical properties with increase in molecular mass.
(v) Chemical properties are similar.
(vi) All members can be prepared by a common method.
To systematically arrive at the IUPAC name of the compound CH3-CH2-CH2-OH, we follow a series of steps. First, identify the longest carbon chain that contains the principal functional group. In this case, the longest carbon chain consists of three carbon atoms, so the root word is 'prop'. Second, determine the type of carbon-carbon bonds present in this chain. Since all bonds between carbon atoms are single bonds, the primary suffix is 'ane'. Third, identify the principal functional group. The compound contains a hydroxyl (-OH) group, indicating that it is an alcohol. Therefore, a secondary suffix is required. Fourth, number the carbon chain starting from the end that is closest to the principal functional group to give it the lowest possible locant number. In CH3-CH2-CH2-OH, numbering from the right gives the -OH group on carbon 1 (CH3-CH2-CH2-OH), while numbering from the left would place it on carbon 3. Thus, we number from the right: 3 2 1 CH3-CH2-CH2-OH. The -OH group is attached to carbon number 1. Finally, combine the root word, primary suffix, and secondary suffix, indicating the position of the functional group. The secondary suffix for an alcohol is '-ol', and its position is indicated by the locant number. Therefore, the IUPAC name is propan-1-ol.
(i) Dilution: Molasses is diluted with water to bring the sugar concentration to about 8-10%.
(ii) Addition of nitrogen source: If needed, ammonium sulphate or ammonium phosphate is added as food for yeast.
(iii) Fermentation: Yeast is added and the mixture is kept at about 303 K. Invertase converts sucrose into glucose and fructose; zymase converts these sugars into ethanol and carbon dioxide.
C6H12O6 -> 2C2H5OH + 2CO2
The fermented liquid is called wash and contains about 8-12% ethanol.
(iv) Distillation: Fractional distillation of wash gives rectified spirit, containing 95.5% ethanol and 4.5% water.
(v) Absolute alcohol: 100% ethanol is obtained by removing the remaining water using an azeotrope-breaking method such as molecular sieves/desiccants or azeotropic distillation.
CH3COOH + NaOH -> CH3COONa + H2O
(ii) Ethanoic acid with sodium bicarbonate:
CH3COOH + NaHCO3 -> CH3COONa + CO2 + H2O
(iii) Oxidation of ethanol by acidified potassium dichromate:
3C2H5OH + 2K2Cr2O7 + 8H2SO4 -> 3CH3COOH + 2Cr2(SO4)3 + 2K2SO4 + 11H2O
(iv) Combustion of ethanol:
C2H5OH + 3O2 -> 2CO2 + 3H2O
The cleansing action of soap is based on its molecular structure and its ability to form structures called micelles. A soap molecule is amphipathic, meaning it has two distinct parts: a polar, ionic head (the carboxylate group, -COO- Na+) and a long, non-polar hydrocarbon tail. The polar head is hydrophilic, meaning it is attracted to water molecules. The non-polar tail is hydrophobic, meaning it is repelled by water but attracted to non-polar substances like oil and grease. When soap is dissolved in water containing dirt or grease, the hydrophobic tails of the soap molecules orient themselves towards the grease particles, while the hydrophilic heads remain in contact with the surrounding water. This arrangement causes the soap molecules to surround the grease particles, forming spherical clusters called micelles. The grease and dirt are trapped within the hydrophobic core of the micelle. The outer surface of the micelle, composed of the hydrophilic heads, allows it to be dispersed in water. When the water is agitated, these micelles, along with the trapped dirt and grease, are lifted from the surface and washed away, thus cleansing the fabric or surface.
(i) Given that the molecular formula of the alcohol is C4H10O and the locant number of its -OH group is 2, we can deduce its structural formula. The parent chain has four carbon atoms (butane). The -OH group is attached to the second carbon atom. Therefore, the structural formula is CH3-CH(OH)-CH2-CH3. (ii) Following the IUPAC nomenclature rules, the parent chain is butane, and the functional group is an alcohol (-OH) located at position 2. Thus, the IUPAC name of this compound is butan-2-ol. (iii) This compound is classified as saturated because its carbon chain contains only single bonds between carbon atoms. The term 'saturated' in organic chemistry refers to hydrocarbons that contain the maximum possible number of hydrogen atoms for a given number of carbon atoms, with no double or triple bonds present in the carbon skeleton.
(ii) It reacts with ethanol in the presence of concentrated H2SO4 to form the sweet-smelling ester ethyl ethanoate, B:
CH3COOH + C2H5OH --conc. H2SO4-> CH3COOC2H5 + H2O
(iii) The process is esterification.
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