| # | Statement (Answer in bold) |
|---|---|
| 1 | A reaction between an acid and a base is called neutralization. |
| 2 | When lithium metal is placed in hydrochloric acid, hydrogen gas is evolved. |
| 3 | The equilibrium attained during the melting of ice is known as physical equilibrium. |
| 4 | The pH of a fruit juice is 5.6. If slaked lime is added to this juice, its pH increases. |
| 5 | The ionic product of water at 25°C (298 K) is Kw = [H+][OH-] = 1.00 × 10^-14. |
| 6 | The normal pH of human blood is 7.35 - 7.45. |
| 7 | Electrolysis is a type of decomposition reaction. |
| 8 | The number of products formed in a synthesis reaction is one. |
| 9 | Chemical volcano is an example of decomposition reaction. |
| 10 | The ion formed by dissolution of H+ in water is called hydronium ion. |
Refer to textbook for match answers.
| # | Statement | Answer | Correction (if False) |
|---|---|---|---|
| 1 | Silver metal can displace hydrogen gas from nitric acid. | False | Silver metal cannot displace hydrogen gas from nitric acid. |
| 2 | The pH of rain water containing dissolved gases like SO3, CO2, NO2 will be less than 7. | True | |
| 3 | At the equilibrium of a reversible reaction, the concentration of the reactants and the products will be equal. | False | At equilibrium, the concentrations of reactants and products remain constant, but they need not be equal. |
| 4 | Periodical removal of one of the products of a reversible reaction increases the yield. | True | |
| 5 | On dipping a pH paper in a solution, it turns into yellow. Then the solution is basic. | False | Yellow on universal pH paper indicates an acidic solution. Neutral solution is green, and basic solution is blue/violet. |
The reaction rate of a chemical reaction increases when the temperature is raised primarily because of an increase in the kinetic energy of the reactant particles. At higher temperatures, particles move faster and collide more frequently. More importantly, a larger proportion of these collisions possess sufficient energy, known as the activation energy, to overcome the energy barrier and lead to a successful reaction. Therefore, both the frequency of collisions and the fraction of effective collisions increase with temperature, resulting in an overall acceleration of the reaction rate.
Example: On burning magnesium in air, it combines with oxygen to form magnesium oxide:
2Mg(s) + O2(g) -> 2MgO(s)
i. It proceeds in both forward and backward directions under suitable conditions.
ii. Forward and backward reactions take place simultaneously.
iii. It can attain dynamic equilibrium.
iv. Reactants and products coexist; reactants are not completely converted into products. Example: N2(g) + 3H2(g) ⇌ 2NH3(g).
Irreversible reaction:
i. It proceeds essentially in one direction under the given conditions.
ii. Equilibrium is not attained.
iii. Reactants can be completely converted into products. Example: 2Mg(s) + O2(g) -> 2MgO(s).
2HgO(s) --heat-> 2Hg(l) + O2(g)
(i) Precipitation reaction: Two aqueous ionic solutions react to form an insoluble salt, called a precipitate.
Pb(NO3)2(aq) + 2KI(aq) -> PbI2(s) + 2KNO3(aq)
(ii) Neutralization reaction: An acid reacts with a base to form salt and water.
HCl(aq) + NaOH(aq) -> NaCl(aq) + H2O(l)
(iii) Gas-evolution reaction: The reaction produces a gas that escapes.
Na2CO3(aq) + 2HCl(aq) -> 2NaCl(aq) + H2O(l) + CO2(g)
(i) Nature of reactants: More reactive substances react faster. Sodium reacts faster with hydrochloric acid than with acetic acid because hydrochloric acid is stronger.
2Na(s) + 2HCl(aq) -> 2NaCl(aq) + H2(g)
(ii) Concentration: Higher concentration gives more particles per unit volume, so collisions are more frequent and the rate increases.
(iii) Temperature: Higher temperature increases kinetic energy and the number of effective collisions.
(iv) Pressure: For gaseous reactants, increased pressure brings particles closer and increases collision frequency.
(v) Catalyst: A catalyst increases reaction rate without being consumed.
(vi) Surface area: Powdered solids react faster than lumps because they have larger surface area for collisions.
(ii) The stomach contains hydrochloric acid, with pH about 2, which helps digestion. Excess acid causes indigestion and can be neutralised by antacids.
(iii) Saliva normally has pH about 6.5 to 7.5. If mouth pH falls below 5.5, tooth enamel starts getting damaged; basic toothpastes help neutralise acids.
(iv) Soil pH is important in agriculture. Different crops need different pH ranges; citrus prefers slightly acidic to neutral soil, rice prefers acidic soil and many crops such as sugarcane prefer near-neutral soil.
(v) Unpolluted rainwater is slightly acidic, about pH 5.6, because dissolved CO2 forms carbonic acid. Polluted air containing oxides of sulphur and nitrogen makes rain more acidic, causing acid rain and harming aquatic life.
Chemical equilibrium is a state achieved in a reversible chemical reaction where the rate of the forward reaction becomes exactly equal to the rate of the backward reaction. At this point, there is no net change in the concentrations of reactants and products, and the system appears to be static. However, it is a dynamic state because both the forward and backward reactions continue to occur at the same pace. The characteristics of chemical equilibrium include: (i) The rates of the forward and backward reactions are equal. (ii) The macroscopic properties of the system, such as pressure, concentration, color, and density, remain constant over time. (iii) The equilibrium is dynamic; reactions are still occurring at the molecular level, but there is no observable change in the overall system. (iv) In the context of physical equilibrium, such as phase changes, the amounts or properties of the different phases remain constant once equilibrium is established.
CO2 + H2O -> H2CO3 (carbonic acid)
A is CaCO3, calcium carbonate. B is CaO, calcium oxide. C is CO2, carbon dioxide, which forms carbonic acid in water.
Ni + CuSO4 -> NiSO4 + Cu
pH of lemon juice = 2
pH = -log10[H+]
Therefore, [H+] = 10^-2 mol L^-1
[H+] = 0.01 mol L^-1
[H+] = 1.0 x 10^-4 M
pH = -log10[H+]
= -log10(1.0 x 10^-4)
= 4
KOH(aq) -> K+(aq) + OH-(aq)
[OH-] = 1 x 10^-5 mol L^-1
pOH = -log10[OH-] = 5
pH + pOH = 14
pH = 14 - 5 = 9
[OH-] = 1 x 10^-11 M
pOH = -log10[OH-] = 11
pH + pOH = 14
pH = 14 - 11 = 3
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